Product ID:P-4 BLEACH BL 4.25 PART A 4.17 LITERS
MSDS Date:09/09/1993
FSC:6750
NIIN:00F047713
Kit Part:Y
MSDS Number: BZDHC

ILFORD PHOTO CORP

W 70 CENTURY RD
PARAMUS, NJ 07653-5000
US

Emergency Phone: 800-842-9660/201-265-6000

Info Phone: 201-265-6000/800-842-9660

Cage: 64145

ILFORD PHOTO CORP

PARAMUS, NJ 07653 US

Telephone: 201-265-6000

Cage: 64145

SULFURIC ACID (CONFIRMED HUMAN CARCINOGEN BY IARC - GROUP

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: 15-30%

OSHA PEL 1 MG/CUM

ACGIH TLV: 1 MG/CUM=IC

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

BENZENESULFONIC ACID, M-NITRO-, SODIUM SALT,

CAS: 127-68-4

RTECS: DB7195000

Fraction By Weight: 5-7%

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 65-70%

LD50 LC50 Mixture:ORAL LD50(RAT): 155 MG/KG SULFURIC ACID
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: CORROSIVE, CAUSES IRREVERSIBLE
DAMAGE & BLINDNESS. SKIN: CORROSIVE, CAUSES BURNS TO MUCOUS
MEMBRANES. INHALATION: MIST IS IRRITANT TO UPPER RESPIRATORY TRACT.
MAY CAUSE PULMONARY EDEMA, COUGHING & SNEEZING. INGESTION: DENTAL
EROSION,BURNS TO MOUTH, THROAT, ESOPHAGUS & STOMACH. (SEE SUPP)
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:BURNS, IRRITANT, EDEMA, COUGHING, SNEEZING,
INFECTIONS.

First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: FLUSH W/WATER THEN
WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR & PERFORM
ARTIFICIAL RESPIRATION. INGESTION: GIVE 4-5 GLASSES OF MILK/WATER.
DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:NON-FLAMMABLE
Extinguishing Media:USE MEDIA PROPER TO PRIMARY SOURCE OF FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:MAY PRODUCE TOXIC FUMES. ACTS AS AN
OXIDIZER.

Spill Release Procedures:NEUTRALIZE. RINSE NEUTRALIZED SOLUTION TO
SEWER IF PERMITTED BY LOCAL AUTHORITIES.
Neutralizing Agent:SODIUM CARBONATE/BAKING SODA.

Handling and Storage Precautions:STORE IN A COOL DRY AREA AWAY FROM
DEVELOPERS, FIXER & STRONG ALKALIS. USE W/ADEQUATE VENTILATION.
Other Precautions:AVOID INHALATION & CONTACT W/SKIN, EYES & CLOTHING.

Respiratory Protection:USE NIOSH APPROVED ACID GAS/ORGANIC VAPOR
RESPIRATOR IF SUFFICIENT VENTILATION ISN'T PROVIDED.
Ventilation:LOCAL EXHAUST: CHANGE MACHINE FILTER AS RECOMMENDED.
MECHANICAL VENTILATION: GOOD ROOM VENTILATION.
Protective Gloves:BUTYL RUBBER
Eye Protection:SAFETY GOGGLES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
HEALTH & SYMPTOMS CON'TD: CHRONIC: INHALATION: MIST/VAPOR CAUSES
BRONCHITIS, FREQUENT RESPIRATORY INFECTIONS, EMPHYSEMA.

Boiling Pt:B.P. Text:>212F
Melt/Freeze Pt:M.P/F.P Text:>32F
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:1.21
pH:<1
Evaporation Rate & Reference:AS WATER
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW LIQUID W/CHARACTERISTIC ODOR.
Percent Volatiles by Volume:69/WT

Stability Indicator/Materials to Avoid:YES
DEVELOPERS, FIXERS, SULFITES
Hazardous Decomposition Products:SULFUR DIOXIDE

Waste Disposal Methods:SOLUTION IS RCRA HAZARDOUS WASTE UNLESS
NEUTRALIZED TO PH 6-8 BEFORE DISPOSAL. BY PERMIT, MAY BE DISCHARGED
TO SANITARY SEWER AFTER NEUTRALIZATION. DISPOSE OF IAW/FEDERAL,
STATE & LOCAL REGULATIONS. C ORROSIVE MATERIAL, UN1830.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.